Published October 21, 1997
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Journal Article
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A terminal molybdenum carbide prepared by methylidyne deprotonation
Abstract
The carbide anion [CMo{N(R)Ar}_3]– [R = C(CD_3)_2CH_3, Ar = C_6H_3Me_2-3,5], is obtained by deprotonation of the corresponding methylidyne compound, [HCMo{N(R)Ar}_3], and is characterized by X-ray diffraction as its {K(benzo-15-crown-5)_2}+ salt, thereby providing precedent for the carbon atom as a terminal substituent in transition-metal chemistry.
Additional Information
© 1997 Royal Society of Chemistry. Received in Bloomington, IN, USA, 17th June 1997; 7/04251E.Attached Files
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