Published August 10, 2011
| Published + Supplemental Material
Journal Article
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Iridium complexes bearing a PNP ligand, favoring facile C(sp^3)–H bond cleavage
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Abstract
Hydrogen iodide is lost upon reaction of PNP with IrI_3, where PNP = 2,6-bis-(di-t-butylphosphinomethyl)pyridine to give crystallographically characterized Ir(PNP)*(I)_2, which reacts with H_2 to give Ir(PNP)(H)(I)_2. Ir(PNP)(Cl)_3 is relatively inert towards the intramolecular C–H activation of the tert-butyl's of the PNP ligand.
Additional Information
© 2011 The Royal Society of Chemistry. Received 4th April 2011. Accepted 6th July 2011. First published on the web 10th August 2011. This material is based upon work supported by Chevron Energy Technology Company, by the Center for Catalytic Hydrocarbon Functionalization, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DOE DE-SC000-1298 and by Scripps Florida.Attached Files
Published - Lokare2011p15829Dalton_Transactions.pdf
Supplemental Material - c1dt10577a.pdf
Supplemental Material - c1dt10577a.txt
Files
c1dt10577a.txt
Additional details
- Eprint ID
- 25415
- Resolver ID
- CaltechAUTHORS:20110922-155211533
- Chevron Energy Technology Company
- Department of Energy (DOE)
- DE-SC000-1298
- Scripps Florida
- Created
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2011-09-23Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field