Published June 29, 2011
| Accepted Version + Supplemental Material
Journal Article
Open
Z-Selective Homodimerization of Terminal Olefins with a Ruthenium Metathesis Catalyst
Chicago
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Abstract
The cross-metathesis of terminal olefins using a novel ruthenium catalyst results in excellent selectivity for the Z-olefin homodimer. The reaction was found to tolerate a large number of functional groups, solvents, and temperatures while maintaining excellent Z-selectivity, even at high reaction conversions.
Additional Information
© 2011 American Chemical Society. Received: April 15, 2011. Published: June 08, 2011. Publication Date (Web): June 8, 2011. This work was financially supported by the NIH (NIH 5R01GM031332-27), the NSF (CHE-1048404), Mitsui Chemicals, Inc. (K.E.), and the NDSEG (fellowship to B.K.K.). Instrumentation facilities at which this work was carried out were supported by NIH RR027690. Materia, Inc. is thanked for its donation of metathesis catalysts.Attached Files
Accepted Version - nihms302355.pdf
Supplemental Material - ja203488e_si_001.pdf
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Additional details
- PMCID
- PMC3138429
- Eprint ID
- 24634
- Resolver ID
- CaltechAUTHORS:20110802-144731917
- NIH
- NIH-5R01GM031332-27
- NSF
- CHE-1048404
- Mitsui Chemicals, Inc.
- National Defense Science and Engineering Graduate (NDSEG) Fellowship
- NIH
- RR027690
- Created
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2011-08-02Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field