Published June 8, 2011
| Supplemental Material
Journal Article
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Dinitrogen Complexes of Sulfur-Ligated Iron
Chicago
Abstract
We report a unique class of dinitrogen complexes of iron featuring sulfur donors in the ancillary ligand. The ligands utilized are related to the recently studied tris(phosphino)silyl ligands (2-R_2PC_6H_4)_3Si (R = Ph, iPr) but have one or two phosphine arms replaced with thioether donors. Depending on the number of phosphine arms replaced, both mononuclear and dinuclear iron complexes with dinitrogen are accessible. These complexes contribute to a desirable class of model complexes that possess both dinitrogen and sulfur ligands in the immediate iron coordination sphere.
Additional Information
© 2011 American Chemical Society. Received: March 7, 2011. Published: May 16, 2011. This work was supported by the NIH (GM070757). Charlene Tsay and Larry Henling are acknowledged for crystallographic assistance. Prof. George Rossman is acknowledged for use of his NIR spectrometer. Dr. Dave Harris is acknowledged for useful discussions of the magnetic data.Attached Files
Supplemental Material - ja2020907_si_001.cif
Supplemental Material - ja2020907_si_002.pdf
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Additional details
- Eprint ID
- 24235
- Resolver ID
- CaltechAUTHORS:20110628-093114193
- NIH
- GM070757
- Created
-
2011-06-28Created from EPrint's datestamp field
- Updated
-
2021-11-09Created from EPrint's last_modified field