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Published April 2011 | Accepted Version
Journal Article Open

M≡E and M=E complexes of iron and cobalt that emphasize three-fold symmetry (E≡O, N, NR)

Abstract

Mid-to-late transition metal complexes that feature terminal, multiply bonded ligands such as oxos, imides, and nitrides have been invoked as intermediates in several catalytic transformations of synthetic and biological significance. Until about ten years ago, isolable examples of such species were virtually unknown. Over the past decade or so, numerous chemically well-defined examples of such species have been discovered. In this context, the present review summarizes the development of 4- and 5-coordinate Fe(E) and Co(E) species under local three-fold symmetry.

Additional Information

© 2011 Elsevier B.V. Received 5 November 2010; accepted 4 January 2011. Available online 13 January 2011. The authors are indebted to our many co-workers and colleagues in the field that have contributed to the work that has been described in this review. JCP is particularly grateful to those students and postdocs that shaped the intellectual principles that now form the basis of our ideas concerning L3M(E) and LL3M(E) systems of iron and cobalt. Wealso wish to acknowledge the various sources of funding that have, over the years, made the relevant work in our labs possible. This includes support from the NIH (GM-070757), the NSF (CHE-0132216 and 0750234), the Dreyfus Foundation, and the Alfred P. Sloan Foundation. CTS is grateful for an NSF Graduate Fellowship.

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Created:
August 22, 2023
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October 23, 2023