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Published 2011 | Supplemental Material + Published
Journal Article Open

Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand

Abstract

Trinuclear complexes of Mn^(II), Fe^(II), Co^(II), Ni^(II), Cu^(II), and Zn^(II) were synthesized using a ligand architecture based upon a 1,3,5- triarylbenzene core decorated with six pyridines and three alkoxide moieties. Characterization via X-ray diffraction, NMR, and magnetism studies is discussed.

Additional Information

© 2011 The Royal Society of Chemistry. Received 16th December 2010, Accepted 14th February 2011. We thank Lawrence M. Henling for crystallographic assistance. We are grateful to Caltech, Chemistry Department Dow Fellowship (JSK), and NSF GRFP (EYT) for funding. The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to Caltech, CHE-0639094. SQUID data were collected at the MMRC of the Beckman Institute of the California Institute of Technology.

Attached Files

Published - Tsui2011p13372Chem_Commun.pdf

Supplemental Material - c0cc05608a.pdf

Supplemental Material - c0cc05608a.txt

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August 19, 2023
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