Published November 15, 2010
| Supplemental Material
Journal Article
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Mechanism of Glucose Isomerization Using a Solid Lewis Acid Catalyst in Water
Chicago
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Abstract
^1H and ^(13)C NMR spectroscopy on isotopically labeled glucose reveals that in the presence of tin-containing zeolite Sn-Beta, the isomerization reaction of glucose in water proceeds by way of an intramolecular hydride shift (see scheme) rather than proton transfer. This is the first mechanistic demonstration of Sn-Beta acting as a Lewis acid in a purely aqueous environment.
Additional Information
© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: July 29, 2010. Published online: October 20, 2010. This work was financially supported as part of the Catalysis Center for Energy Innovation, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC00010004. M.M. acknowledges Fundación Ramón Areces Postdoctoral Research Fellowship Program for financial support.Attached Files
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Additional details
- Eprint ID
- 21467
- Resolver ID
- CaltechAUTHORS:20101221-084907268
- Department of Energy (DOE)
- DE-SC00010004
- Fundacion Ramon Areces
- Created
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2011-01-12Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field