Published June 1, 2010
| public
Journal Article
Access to Well-Defined Ruthenium(I) and Osmium(I) Metalloradicals
Abstract
Radically complex: Well-defined mononuclear RuI and OsI complexes (see scheme) have metalloradical character, as indicated by EPR spectroscopy and DFT calculations. The Ru^I and Os^I metalloradicals exhibit both one-electron and two-electron redox reactivity. The latter process affords unusual imido complexes with substantial radical character on the {ArN} moiety.
Additional Information
© 2010 Wiley. Received: 26 February 2010; Published online: May 7, 2010. This work was supported by the NIH (GM070757). Samantha MacMillan and Dr. Peter Mller are acknowledged for crystallographic assistance. The NSF is acknowledged for use of instruments at the MIT DCIF (CHE-9808061, DBI-97299592).Additional details
- Eprint ID
- 18957
- DOI
- 10.1002/anie.201001199
- Resolver ID
- CaltechAUTHORS:20100709-101044545
- GM070757
- NIH
- CHE-9808061
- NSF
- DBI-97299592
- NSF
- Created
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2010-07-09Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field