Published March 19, 2010
| Supplemental Material
Journal Article
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Regioselective Reactions of Highly Substituted Arynes
Chicago
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Abstract
The fully regioselective reactivity of four new highly substituted silyl aryl triflate aryne precursors in aryne acyl-alkylation, acyl-alkylation/condensation, and heteroannulation reactions is reported. The application of these more complex arynes provides access to diverse natural product scaffolds and obviates late-stage functionalization of aromatic rings.
Additional Information
© 2010 American Chemical Society. Published In Issue: March 19, 2010; article ASAP: February 18, 2010; received: January 12, 2010. The authors thank The Gordon and Betty Moore Foundation, Abbott, Amgen, Boehringer- Ingelheim, Bristol-Myers Squibb, Merck, Sigma-Aldrich, Teva USA Scholars grant, The California HIV/AIDS Research Program (fellowship to P.M.T.) and Caltech for generous funding.Attached Files
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Additional details
- Eprint ID
- 17854
- Resolver ID
- CaltechAUTHORS:20100405-115154177
- Gordon and Betty Moore Foundation
- Abbot
- Amgen
- Boehringer-Ingelheim
- Bristol-Myers Squibb
- Merck
- Sigma-Aldrich
- Teva USA Scholars grant
- California HIV/AIDS Research Program
- Caltech
- Created
-
2010-04-06Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field