Published February 22, 2010
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Journal Article
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Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C−H Activation
Chicago
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Abstract
η^3-Cyclohexenyl and -indenyl Pt(II) and Pd(II) diimine complexes, which are generated via C−H activation of cyclohexene and indene by Pt and Pd hydroxy dimers, are selectively oxidized by Br_2, Na_2PtCl_6, and CuCl_2 to give halogenated organic products along with well-defined Pd(II) and Pt(II) species.
Additional Information
© 2010 American Chemical Society. Received July 30, 2009. Publication Date (Web): January 15, 2010. We thank Larry Henling and Mike Day for X-ray crystallographic characterization of complexes and BP for financial support through the MC^2 program.Attached Files
Supplemental Material - om900678z_si_001.cif
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Additional details
- Eprint ID
- 17692
- Resolver ID
- CaltechAUTHORS:20100308-111005616
- BP MC2 program
- Created
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2010-03-09Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field