Ra-partitioning between phlogopite and silicate melt and ^(226)Ra/Ba–^(230)Th/Ba isochrons
Abstract
In this study we experimentally determine phlogopite/melt partition coefficients of Ra and other trace elements in a lamproitic system. This work was achieved using an analytical technique (LA-ICP-MS) with low detection limits (~0.01 fg) permitting the measurement of the very low Ra concentrations feasible in experiments (~1 ppb). D_(Ra)^(phlogopite/melt) was determined to 2.28 ± 0.44 and 2.84 ± 0.47 in two experiments, the ratio D_(Ra)/D_(Ba) is around 1.6. The compatibility of Ra in phlogopite results from an ionic radius being close to the apex of the lattice strain parabola for earth alkalis in the large XII-coordinated interlayer site of phlogopite. A re-evaluation of D_(Ra) and D_(Ra)/D_(Ba) for magmatic minerals containing appreciable Ra, yields D_(Ra)^(mineral/melt) ranging from ~2.6 for phlogopite down to 2–3 • 10^(−5) for pyroxenes, and D_(Ra)/D_(Ba)^(mineral/melt) from ~4 for leucite to 2 • 10^(−2) for orthopyroxene. The influence of melt composition on D_(Ra)/D_(Ba) is less than 10%. All investigated minerals have different D_(Ra)/D_(Ba), strongly fractionating Ra from Ba. Thus, for magmatic systems, (^(226)Ra)/Ba in the various minerals is not constant, these minerals do not form a straight line in the (^(226)Ra)/Ba–(^(230)Th)/Ba system at the time of crystallization and thus, there is no (^(226)Ra)/Ba–(^(230)Th)/Ba isochron at t_0. 226Ra–230Th–Ba mineral dating is thus applicable only to model ages calculated from mineral–glass pairs with known D_(Ra).
Additional Information
© 2009 Elsevier B.V. Received 1 January 2009; revised 3 August 2009; accepted 6 August 2009. Available online 21 August 2009. The authors thank Kathrin Hametner and Max Ruethi for their technical help. Georg Zellmer and an anonymous reviewer provided helpful comments.Additional details
- Eprint ID
- 17658
- DOI
- 10.1016/j.lithos.2009.08.004
- Resolver ID
- CaltechAUTHORS:20100304-095021967
- Created
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2010-03-12Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field