Published September 25, 2009
| Accepted Version + Supplemental Material
Journal Article
Open
Tunable, Temperature-Responsive Polynorbornenes with Side Chains Based on an Elastin Peptide Sequence
- Creators
- Conrad, Rosemary M.
-
Grubbs, Robert H.
Chicago
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Abstract
Random copolymers made by living ring-opening metathesis polymerization of norbornene monomers containing either the elastin peptide sequence -(VPGVG)- or pentaethylene glycol (see scheme; Mes=mesityl, pyr=pyridine) exhibit a lower critical solution temperature (LCST). The LCST can be easily modified by varying the ratio of the co-monomers in the polymer feed.
Additional Information
© 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: July 15, 2009. Published online: September 25, 2009. We thank the National Institutes of Health (5RO1 GM31332, F32 HL091440) and the Beckman Institute at Caltech (postdoctoral fellowship to R.M.C.). We acknowledge Gretchen Keller and Prof. Harry Gray for use of the UV/Vis spectrophotometer. Supporting information for this article is available on the WWW under http://dx.doi.org/10.1002/anie.200903888.Attached Files
Accepted Version - nihms187586.pdf
Supplemental Material - Conrad2009p6365Angew_Chem_Int_Edit_supp.pdf
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Conrad2009p6365Angew_Chem_Int_Edit_supp.pdf
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Additional details
- PMCID
- PMC3517114
- Eprint ID
- 16759
- DOI
- 10.1002/anie.200903888
- Resolver ID
- CaltechAUTHORS:20091119-110433776
- NIH
- 5RO1 GM31332
- NIH Postdoctoral Fellowship
- F32 HL091440
- Caltech Beckman Institute
- Created
-
2010-01-04Created from EPrint's datestamp field
- Updated
-
2021-11-08Created from EPrint's last_modified field