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Published April 15, 1986 | public
Journal Article Open

Dielectric relaxation and intramolecular electron transfers

Abstract

Intramolecular charge transfer are considered for the case that the motion of the system is on a single potential energy surface. The case where this motion occurred on two surfaces was considered elsewhere. The former is shown to be much preferable for studies of solvent dynamics. Several aspects of the relation between "constant charge" dielectric relaxation time of the polar solvent and the experimental decay time of emission from the polar excited state of the solute are discussed for hydrogen-bonded systems.

Additional Information

Copyright © 1986 American Institute of Physics (Received 29 July 1985; accepted 16 January 1986) The support of this research by a grant from the Ministry of Education of Japan (to H.S.) and from the National Science Foundation (to R.A.M.) is gratefully acknowledged.

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