Published December 15, 1983
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Journal Article
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Doublet→quartet and doublet→doublet electronic transitions in NO2 by electron impact
- Creators
- Rianda, R.
- Frueholz, R. P.
- Kuppermann, A.
Abstract
The electron-impact energy-loss spectrum of nitrogen dioxide (NO2) has been measured at impact energies of 25, 50, and 75 eV, and scattering angles varying from 5° to 80°. A previously unreported spin-forbidden doublet→quartet transition was observed at 4.49 eV, in excellent agreement with theoretical calculations. Doublet→doublet transitions were observed at 2.95, 5.81, 7.48, 8.64, 9.69, 10.52, 10.68, 10.94, and 11.20 eV, in agreement with previous experimental and theoretical work. In addition, numerous doublet→doublet transitions to superexcited states were observed.
Additional Information
Copyright © 1983 American Institute of Physics. Received 8 July 1983; accepted 16 August 1983. This work was supported in part by the U.S. Department of Energy, Contract No. DE-AM03-76F00767; Project Agreement No. DE-AT03 76ER72004. Work performed [by R.R.] in partial fulfillment of the requirements for the Ph.D. degree in Chemistry at the California Institute of Technology. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 6862.Files
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Additional details
- Eprint ID
- 10686
- Resolver ID
- CaltechAUTHORS:RIAjcp83
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