Published March 8, 2001
| Published
Journal Article
Open
Excitation of the symmetry forbidden bending mode in molecular photoionization
Abstract
We present results on the energy dependence of the vibrational branching ratio for the bending mode in CO2 3sigmau-1 photoionization. Specifically, we determine the v+ = (0,1,0)/v+ = (0,0,0) intensity ratio by detecting dispersed fluorescence from the electronically excited photoions. The results exhibit large deviations over a very wide energy range, 18
Additional Information
© 2001 American Institute of Physics. Received 6 October 2000; accepted 19 December 2000. We thank the CAMD staff for their assistance, and EDP acknowledges support from the National Science Foundation (CHE-9616908). This work was also supported in part by the Robert A. Welch Foundation (Houston, Texas) under Grant No. A-1020. We also acknowledge the support of the Texas A&M University Supercomputing Facility. Finally, we wish to acknowledge helpful conversations with Dr. M.G. White of Brookhaven National Laboratory.Attached Files
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- Eprint ID
- 11036
- Resolver ID
- CaltechAUTHORS:MILjcp01
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2008-06-24Created from EPrint's datestamp field
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2021-11-08Created from EPrint's last_modified field