Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published 2005 | Published + Supplemental Material
Journal Article Open

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as –0.28 V vs. SCE.

Additional Information

© Royal Society of Chemistry 2005 Received (in Berkeley, CA, USA) 28th June 2005, Accepted 29th July 2005. First published on the web 23rd August 2005 For financial support we acknowledge the NSF through a Chemical Bonding Center (CBC). We also thank Prof. Alex Sessions for his generous help with the gas chromatography experiments.

Attached Files

Published - HUXcc05.pdf

Supplemental Material - HUXcc05supp.pdf

Files

HUXcc05.pdf
Files (676.4 kB)
Name Size Download all
md5:fb5f2ac0b662bf6bb7f6d8f01204cf72
269.3 kB Preview Download
md5:5c834a8b15d91bb2ad94ce532d9a7b1d
2.3 kB Preview Download
md5:5c369fe42c4e1035f70daebcb2cd39cd
377.5 kB Preview Download
md5:4ce1b6514c75f3688ae65e775ec79f70
12.1 kB Preview Download
md5:c19d527083ac96f9a927f0ad4e8fa2df
15.2 kB Preview Download

Additional details

Created:
August 22, 2023
Modified:
October 16, 2023