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Published August 1936 | Published
Journal Article Open

Thermodynamic Properties of Phosphorus Compounds

Abstract

With Raman spectrum, electron diffraction and existing equilibrium data the standard virtual entropies of P(s, white), P4(g). PCl3(g), PCl3(l), PCl5(g), and PCl5(s) are calculated to be 10.55, 66.88, 74.7, 52.8, 87.7, and 40.8 cal./deg. respectively. The corresponding standard free energies of formation are calculated to be (0), 5850, —64,650, —63,570, —72,540 and —77,950 cal., respectively.

Additional Information

Copyright © 1936 American Institute of Physics. Received June 13, 1936. Gates Chemical Laboratory, Publication No. 551

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August 21, 2023
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