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Published November 1958 | public
Journal Article Open

Infrared Absorption Associated with Strong Hydrogen Bonds

Abstract

Several investigators have proposed that there exists a more or less unique relation between the O-O distance in O-H-O hydrogen bonds and the shift of O-H vibrational frequency. [1-5] However, the meager intensities of some bands which have been ascribed to this vibration (notably in nickel dimethyl-glyoxime and potassium dihydrogen phosphate) have made us a little skeptical of the correlation inthe case of very short, and possibly symmetrical, hydrogen bonds.

Additional Information

Copyright © 1958 American Institute of Physics (Received April 24, 1958) Gates and Crellin Laboratories of Chemistry Contribution No. 2331

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August 21, 2023
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