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Published July 2018 | Published
Journal Article Open

Rotational spectroscopy of the two conformers of 3-methylbutyronitrile (C_4H_9CN) between 2 and 400 GHz

Abstract

We present high-resolution rotational spectroscopy of the two conformers of 3-methylbutyronitrile (C_4H_9CN). Spectra were taken between 2 and 24 GHz by means of Fourier transform microwave spectroscopy. Spectra between 36 and 403 GHz were recorded by means of frequency modulated (FM) absorption spectroscopy. The analysis yields precise rotational constants and higher order distortion constants, as well as a set of ^(14)N nuclear electric quadrupole coupling parameters for each of the two conformers. In addition, quantum chemical calculations were performed in order to assist the assignments. Frequency calculations yield insight into the vibrational energy structure of the two conformers, from which partition functions and vibrational correction factors are determined. These factors are used to determine experimentally and computationally the energy difference between the two conformers, which is revealed to be negligible. Overall, this study provides precise spectroscopic constants for the search of 3-methylbutyronitrile in the interstellar medium. In particular, this molecule is a perfect test case for our knowledge of branched molecule formation in space.

Additional Information

© 2018 ESO. Article published by EDP Sciences. Received 9 March 2018; Accepted 10 April 2018; Published online 27 July 2018. We thank Oliver Zingsheim and Dennis Wachsmuth for help during the FTMW measurements in Hannover. We are grateful to Arnaud Belloche for communicating the results of a search for 3-methylbutyronitrile in the EMoCA survey. This work has been supported by the Deutsche Forschungsgemeinschaft (DFG) through the collaborative research grant SFB 956 "Conditions and Impact of Star Formation", project areas B4 and B3. Olivia Wilkins acknowledges support from a Fulbright U.S. Student Research Award.

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August 19, 2023
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October 18, 2023