Oxidation of Dimethylplatinum(II) Complexes with Dioxygen

Creators: Rostovtsev, Vsevolod V.; Labinger, Jay A.; Bercaw, John E.; Lasseter, Tami L.; Goldberg, Karen I.

Abstract

Dimethylplatinum(II) complexes (L−L)Pt(CH_3)_2 (L−L = bpy, phen, tmeda) are oxidized by dioxygen in methanol to the corresponding alkoxoplatinum(IV) complexes (L−L)Pt(CH_3)_2(OH)(OCH_3).

Additional Information

© 1998 American Chemical Society. Received June 26, 1998. V.V.R./J.A.L./J.E.B. thank the Army Research Office and the National Science Foundation for providing financial support for this work. K.I.G./T.L.L. acknowledge the National Science Foundation and the donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research. K.I.G. is an Alfred P. Sloan Research Fellow.

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Resource type: Journal Article
Publisher: American Chemical Society
Published in: Organometallics, 17(21), 4530-4531, ISSN: 0276-7333.

Created:: August 19, 2023
Modified:: October 18, 2023