Published May 29, 2018
| Supplemental Material
Journal Article
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Phase Directing Ability of an Ionic Liquid Solvent for the Synthesis of HER-Active Ni_2P Nanocrystals
Abstract
An ionic liquid (IL) solvent was used to synthesize small, phase-pure nickel phosphide (Ni_2P) nanocrystals. In contrast, under analogous reaction conditions, substitution of the IL for the common high-boiling organic solvent 1-octadecene (ODE) results in phase-impure nanocrystals. The 5 nm Ni_2P nanocrystals prepared in IL were electrocatalytically active toward the hydrogen evolution reaction. The synthesis in IL was also extended to alloyed Ni_(2–x)Co_xP nanocrystals, where 0.5 ≤ x ≤ 1.5.
Additional Information
© 2018 American Chemical Society. Received: February 13, 2018; Accepted: May 3, 2018; Published: May 3, 2018. R.L.B. acknowledges NSF for supporting the synthetic chemistry under CMMI-1728649. N.S.L. acknowledges NSF for supporting the electrochemical characterization work under the NSF CCI Solar Fuels Program CHE-1305124. C.G.R. acknowledges the Resnick Sustainability Institute for a postdoctral fellowship. The authors declare no competing financial interest.Attached Files
Supplemental Material - ae8b00213_si_001.pdf
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Additional details
- Alternative title
- Phase Directing Ability of an Ionic Liquid Solvent for the Synthesis of HER-Active Ni2P Nanocrystals
- Eprint ID
- 86213
- DOI
- 10.1021/acsaem.8b00213
- Resolver ID
- CaltechAUTHORS:20180503-144511877
- CMMI-1728649
- NSF
- CHE-1305124
- NSF
- Resnick Sustainability Institute
- Created
-
2018-05-03Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field
- Caltech groups
- CCI Solar Fuels, Resnick Sustainability Institute