Published March 2018
| public
Conference Paper
Olefin trimerization and ethylene tandem conversion to linear low density polyethylene
- Creators
- Bercaw, John E.
Abstract
Supporting a titanium catalyst (FI)TiCl_3 (FI = (N-(5-methyl-3-(1-adamantyl)salicylidene)-2'-(2"-methoxyphenyl) anilinato) onto MAO/silica affords a more active catalytic system for ethylene and 1-olefin trimerization. Cosupporting the (FI)TiCl_3 catalyst with the ethylene polymn. catalyst (CpSiNR)TiCl_2 (CpSiNR = (C5Me4) SiMe_2NCMe_3), either on sep. or the same MAO/silica particles, affords a catalyst system for producing butyl-branched LLDPE from and ethylene-only feed. Recent expts. aimed at defining the mechanism and LLDPE structure will be described.
Additional Information
© 2018 American Chemical Society.Additional details
- Eprint ID
- 85844
- Resolver ID
- CaltechAUTHORS:20180413-141330194
- Created
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2018-04-13Created from EPrint's datestamp field
- Updated
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2019-10-03Created from EPrint's last_modified field