Published November 24, 1987
| public
Book Section - Chapter
New Methods for Acquiring IR Spectral Data in Organometallic Chemistry and Catalysis
- Creators
- Darensbourg, Donald J.
- Gibson, Guy
Abstract
The advent of new infrared sampling accessories has allowed in situ study of organometallic systems under conditions that were previously not readily accessible. The techniques of Cylindrical Internal Reflectance (CIR) and Diffuse Reflectance spectroscopies are described herein. The CIR phenomenon was employed in three different apparatus. Two different high pressure CIR cells were used to study reactions homogeneously catalyzed by [μ-HW_2(CO)_(10)]^-. Low temperature reactions of Mo and W complexes were studied using an ambient pressure CIR cell. The diffuse reflectance technique was employed to study powdered samples of Ru carbonyl complexes supported on Al_2O_3.
Additional Information
© 1987 American Chemical Society. Received September 14, 1987. We are most appreciative to Spectra Tech Inc., 652 Glenbrook Road, P. 0. Box 2215, Stamford, CT 06906 for their generous support of our research efforts. We thank Siegfried Jenner, Erich Siegel, and Gabor Faludi of the Caltech Glass Shop for their assistance. Our research in inorganic photochemistry is supported by the National Science Foundation. This is Contribution No. 7486 from the Arthur Amos Noyes Laboratory.Additional details
- Eprint ID
- 85628
- Resolver ID
- CaltechAUTHORS:20180405-083033875
- Spectra Tech Inc.
- NSF
- Created
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2018-04-05Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field
- Series Name
- ACS Symposium Series
- Series Volume or Issue Number
- 357
- Other Numbering System Name
- Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 7486