Published December 10, 2001
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Journal Article
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A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts
Abstract
The ruthenium complex (IMesH_2)(Cl)_2(C_5H_5N)_2Ru═CHPh [IMesH_2 = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene] (3) was prepared by the reaction of (IMesH_2)(PCy_3)(Cl)_2Ru═CHPh (2) with an excess of pyridine. Complex 3 contains substitutionally labile pyridine and chloride ligands and serves as a versatile starting material for the synthesis of new ruthenium benzylidenes.
Additional Information
© 2001 American Chemical Society. Received 5 July 2001. Published online 3 November 2001. Published in print 1 December 2001. Lawrence Henling and Michael Day are acknowledged for the X-ray crystallographic study described herein. The authors would like to thank the NSF for generous funding of this research. J.A.L. thanks the NIH for a postdoctoral fellowship.Attached Files
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Additional details
- Eprint ID
- 79914
- DOI
- 10.1021/om010599r
- Resolver ID
- CaltechAUTHORS:20170808-091344080
- NSF
- NIH Postdoctoral Fellowship
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2017-08-09Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field