Conversion of Acid Chlorides to Substituted Acetylenes with Tungsten Alkylidynes

Creators: Connell, Brian T.; Kirkland, Thomas A.; Grubbs, Robert H.

Abstract

Our investigation into the conversion of acid chlorides to substituted acetylenes using tungsten alkylidynes is presented. Several acid chlorides can be converted to acetylenes in good yields, although a more straightforward synthesis of the required tungsten alkylidynes would be desirable.

Additional Information

© 2005 American Chemical Society. Received 4 May 2005. Published online 17 August 2005. Published in print 1 September 2005. We are grateful to the NIH for funding. B.T.C. thanks the American Cancer Society for postdoctoral support.

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Resource type: Journal Article
Publisher: American Chemical Society
Published in: Organometallics, 24(19), 4684-4686, ISSN: 0276-7333.

Created:: August 19, 2023
Modified:: October 26, 2023