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Published March 29, 2007 | Supplemental Material
Journal Article Open

Ruthenium-Catalyzed Ring-Closing Metathesis to Form Tetrasubstituted Olefins

Abstract

Increased efficiency for ring-closing metathesis to form tetrasubstituted olefins using N-heterocyclic carbene ligated ruthenium catalysts was achieved by reducing the size of the substituents at the ortho positions of the N-bound aryl rings.

Additional Information

© 2007 American Chemical Society. Received 25 January 2007. Published online 8 March 2007. Published in print 1 March 2007. We gratefully acknowledge Alexandre Pletnev of Materia, Inc. for work on the synthesis of 12 and Jean Li of The California Institute of Technology for preparing 14 and 18. T.R. thanks the German Academic Exchange Service (DAAD) for a postdoctoral fellowship. K.C. thanks the NSERC for a postdoctoral fellowship.

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August 19, 2023
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