Published October 4, 2001
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Enantioselective Ruthenium-Catalyzed Ring-Closing Metathesis
Abstract
The first enantioselective ruthenium olefin metathesis catalysts have been prepared, and high enantiomeric excesses (up to 90%) are observed in the desymmetrization of achiral trienes. A model consistent with the stereochemical outcome of the reactions is described and suggests side-on olefin binding and reorganization of the halide ligands.
Additional Information
© 2001 American Chemical Society. Received 13 August 2001. Published online 8 September 2001. Published in print 1 October 2001. This work was supported by the National Institutes of Health. The authors also thank Lawrence M. Henling and Dr. Michael W. Day for solving the crystal structure of complex 9, Tina Trnka and Arnab Chatterjee for supplying isopinocampheol catalyst, and Drs. Melanie Sanford and Jennifer Love for many helpful discussions.Attached Files
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