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Published August 28, 2006 | Supplemental Material
Journal Article Open

Rearrangement of N-Heterocylic Carbenes Involving Heterocycle Cleavage

Abstract

In two similar but unrelated cases, a novel type of ring-opening reaction of N-heterocyclic carbenes (NHCs) was observed. These compounds may represent a general class of hitherto unknown decomposition products of NHCs

Additional Information

© 2006 American Chemical Society. Received 16 June 2006. Published online 2 August 2006. Published in print 1 August 2006. We thank Mr. Larry Henling and Dr. Mike Day for X-ray crystallographic analysis. A.W.W. thanks the Rohm and Haas Corporation for funding. T.R. thanks the German Academic Exchange Service (DAAD) for a postdoctoral fellowship.

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Supplemental Material - om060528ysi20060616_082425.cif

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Supplemental Material - om060528ysi20060724_091103.pdf

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August 19, 2023
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