Published March 26, 2007
| Supplemental Material
Journal Article
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Mechanistic Analysis of Iridium Heteroatom C−H Activation: Evidence for an Internal Electrophilic Substitution Mechanism
Abstract
The mechanism responsible for C−H activation in Ir(acac)_2(OCH_3)(C_6H_6) has been identified and described as an internal electrophilic substitution (IES) mechanism, on the basis of orbital changes and predicted reactivity. In this IES mechanism, the lone pair on a M−X ligand forms an X−H bond, while the orbital making up the M−X bond turns into a coordinating lone pair.
Additional Information
© 2007 American Chemical Society. Received 29 December 2006. Published online 23 February 2007. Published in print 1 March 2007. We thank Chevron Energy Technology Co., the National Science Foundation (Grant No. CHE-0328121), and the ONR (Grant No. MURI-N00014-02-1-0665) for financial support.Attached Files
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Additional details
- Eprint ID
- 79335
- DOI
- 10.1021/om061189b
- Resolver ID
- CaltechAUTHORS:20170725-110427930
- Chevron Energy Technology Co.
- CHE-0328121
- NSF
- N00014-02-1-0665
- Office of Naval Research (ONR)
- Created
-
2017-07-25Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field