Structural, Electrochemical, and Photophysical Properties of Gallium(III) 5,10,15-Tris(pentafluorophenyl)corrole

Creators: Bendix, Jesper; Dmochowski, Ivan J.; Gray, Harry B.; Mahammed, Atif; Simkhovich, Liliya; Gross, Zeev

Abstract

High quantum yields are found for the prototype metallocorrole 1, which is readily prepared from GaCl_3 and tris(pentafluorophenyl)corrole. The crystallographic and electronic structures of 1 are reported as well as the simple generation of its π-cation radical complex by chemical oxidation and the characteristic spectroscopic features of this ion.

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© 2000 Wiley-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany. Issue online: 14 November 2000; Version of record online: 14 November 2000; Manuscript Received: 26 June 2000. We acknowledge support of this research from the Fund for the Promotion of Research at the Technion (Z.G.), the National Science Foundation (H.B.G.), and the Danish Natural Science Research Council for financial support under grant No. 9800549 (J.B.). We also thank Dr. H. Weihe (University of Copenhagen) for access to computing facilities, and L. M. Henling (Beckman Institute) for assistance with the crystal structure determination.

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Structural, Electrochemical, and Photophysical Properties of Gallium(III) 5,10,15-Tris(pentafluorophenyl)corrole

Abstract

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