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Published June 1, 2001 | public
Journal Article

High-Valent Manganese Corroles and the First Perhalogenated Metallocorrole Catalyst

Abstract

On pyrrole! The pyrrole-based corrole ligands can offer an alternative to porphyrin systems. The manganese corroles 1–4 are readily synthesized, undergo metal- not ligand-based redox chemistry, and 4 in particular shows impressive catalytic activity in the oxygenation of styrene with iodosylbenzene.

Additional Information

© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany. Issue online: 28 May 2001. Version of Record online: 28 May 2001. Manuscript Received: 17 Jan 2001. This research (No. 368/00) was supported by the Israel Science Foundation (Z.G.), the US National Science Foundation (H.B.G.), and the Fund for the Promotion of Research at the Technion (Z.G.).

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023