Published October 2, 2003
| public
Journal Article
Using the Marcus Inverted Region for Rectification in Donor−Bridge−Acceptor "Wire" Assemblies
Abstract
We examine the properties of a system in which a hopping mechanism can exploit the nuclear factors, along with the field resulting from the applied voltage, to control the current through a donor−bridge−acceptor (D−B−A) system inserted between two metal electrodes. We find that, by utilizing D/A couples with small λ values, switching can be achieved at modest applied potentials.
Additional Information
© 2003 American Chemical Society. Received 2 June 2003. Published online 9 September 2003. Published in print 1 October 2003. This research was carried out at Brookhaven National Laboratory under contract DE-AC02-98CH10886 with the U.S. Department of Energy, supported by its Division of Chemical Sciences, Office of Basic Energy Sciences, and at the California Institute of Technology by the Arnold and Mabel Beckman Foundation. We are indebted to S. W. Feldberg and R. A. Marcus for invaluable discussions.Additional details
- Eprint ID
- 77700
- DOI
- 10.1021/jp035542s
- Resolver ID
- CaltechAUTHORS:20170524-092031289
- DE-AC02-98CH10886
- Department of Energy (DOE)
- Arnold and Mabel Beckman Foundation
- Created
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2017-05-24Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field