CH Activation with an O-Donor Iridium−Methoxo Complex

Creators: Tenn, William J., III^{1, 2}; Young, Kenneth J. H.^{1, 2}; Bhalla, Gaurav^{1, 2}; Oxgaard, Jonas^{1, 2}; Goddard, William A., III^{1, 2}; Periana, Roy A.^{1, 2}

1. University of Southern California
2. California Institute of Technology

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Abstract

A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex.

Additional Information

© 2005 American Chemical Society. Received 9 March 2005. Published online 27 September 2005. Published in print 1 October 2005. The authors acknowledge the National Science Foundation (CHE-0328121) and Chevron Energy Technology Company for financial support for this research, M. Yousufuddin and Prof. Robert Bau for solving the crystal structure of 2-Py, and Steven K. Meier for synthetic assistance.

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