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Published October 19, 2005 | Supplemental Material
Journal Article Open

CH Activation with an O-Donor Iridium−Methoxo Complex

Abstract

A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex.

Additional Information

© 2005 American Chemical Society. Received 9 March 2005. Published online 27 September 2005. Published in print 1 October 2005. The authors acknowledge the National Science Foundation (CHE-0328121) and Chevron Energy Technology Company for financial support for this research, M. Yousufuddin and Prof. Robert Bau for solving the crystal structure of 2-Py, and Steven K. Meier for synthetic assistance.

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Supplemental Material - ja051497lsi20050914_102456.pdf

Supplemental Material - ja051497lsi20050914_102510.cif

Supplemental Material - ja051497lsi20050914_102523.cif

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August 19, 2023
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