Published August 25, 2004
| Submitted + Supplemental Material
Journal Article
Open
A Stable Four-Membered N-Heterocyclic Carbene
Abstract
The synthesis of the first four-membered N-heterocyclic carbene is described. Depending on the substituents on the nitrogen atoms, it is possible to characterize at room temperature the carbene dimer or the free carbene. Crystallographic analyses are provided for these carbene species.
Additional Information
© 2004 American Chemical Society. Received 13 April 2004. Published online 3 August 2004. Published in print 1 August 2004. We thank Lawrence M. Henling and Michael W. Day for X-ray crystallography studies. E.D.-A. is grateful to the Ministère des Affaires Etrangères (France) for a Lavoisier postdoctoral fellowship. This work was supported by the National Science Foundation.Attached Files
Submitted - ja047892dsi20040413_013321.cif
Supplemental Material - ja047892dsi20040413_013058.cif
Supplemental Material - ja047892dsi20040604_055148.pdf
Supplemental Material - ja047892dsi20040604_055348.cif
Files
ja047892dsi20040604_055148.pdf
Additional details
- Eprint ID
- 76765
- Resolver ID
- CaltechAUTHORS:20170420-115314751
- NSF
- Ministère des Affaires Etrangères
- Created
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2017-04-20Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field