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Published July 16, 2006 | Supplemental Material
Journal Article Open

Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer

Abstract

The facile conversion of M−R to M−OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer−Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.

Additional Information

© 2006 American Chemical Society. Received April 18, 2006. Publication Date (Web): June 27, 2006. The authors acknowledge the National Science Foundation (CHE-0328121) and Chevron Energy Technology Company for financial support of this research.

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