Published February 11, 2013
| Supplemental Material
Journal Article
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Diastereoselective Povarov-Like Reaction Involving O-Pivaloylated D-Galactosylimine
Abstract
A diastereoselective Povarov-like reaction using O-pivaloylated β-D-galactosylamine as the chiral auxiliary is described. The three-component reaction of chiral aldimines, cyclic enol ethers and nucleophiles afforded the desired products in good yields and high content of the main isomer. This procedure provides an efficient method to obtain multifunctional molecules carrying three contiguous chiral centers in high stereoselectivity.
Additional Information
© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: August 24, 2012; Published online: January 9, 2013. This work was supported by grants from the National Natural Science Foundation of China (NSFC) (No. 21072017, 20732001).Attached Files
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Additional details
- Eprint ID
- 75533
- DOI
- 10.1002/adsc.201200761
- Resolver ID
- CaltechAUTHORS:20170330-073929213
- 21072017
- National Natural Science Foundation of China
- 20732001
- National Natural Science Foundation of China
- Created
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2017-03-30Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field