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Published June 1999 | Published + Supplemental Material
Journal Article Open

The red form of [Re(phen)(CO)_3(H_2O)]CF_3SO_3•H_2O

Abstract

The coordination geometry of the cations in the red form of aquatricarbonyl(1,10-phenanthroline-N, N')rhenium(I) trifluoromethanesulfonate hydrate, [Re(C_(12)H_8N_2)(CO)_3- (H_2O)]CF_3SO_3•H_2O, is approximately octahedral, with a facial arrangement of the linearly coordinated carbonyl ligands. The phenanthroline (phen) ligands interleave to form a columnar r-stacked structure.

Additional Information

© 1999 International Union of Crystallography. (Received 14 September 1998; accepted 26 January 1999) We thank L. M. Henling for expert assistance and helpful discussions. This work was supported by the National Science Foundation and the National Institutes of Health.

Attached Files

Published - bk1449.pdf

Supplemental Material - 1.cif

Supplemental Material - HKL.txt

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August 19, 2023
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