Published March 20, 2003
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Journal Article
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Palladium-Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs_2CO_3/t-BuOH
Abstract
The addition of Cs_2CO_3 and t-BuOH provides a dramatic rate acceleration in the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols while maintaining the selectivity of the process.
Additional Information
© 2003 American Chemical Society. Received 13 December 2002. Published online 14 February 2003. Published in print 1 March 2003. We wish to thank the NIH-NIGMS (R01 GM65961-01), the California Institute of Technology, the Camille and Henry Dreyfus Foundation (New Faculty Award to B.M.S.), the Merck Research Laboratories, Research Corporation, The University of California TRDRP (predoctoral fellowship to J.T.B.), the National Science Foundation (predoctoral fellowship to E.M.F.), GlaxoSmithKline, and Abbott Laboratories for generous financial support.Attached Files
Supplemental Material - ol027463psi20030203_123157.pdf
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Additional details
- Eprint ID
- 74472
- Resolver ID
- CaltechAUTHORS:20170222-145100100
- R01GM65961-01
- NIH
- Caltech
- Camille and Henry Dreyfus Foundation
- Merck Research Laboratories
- Research Corporation
- California Tobacco-Related Disease Research Program
- NSF Predoctoral Fellowship
- GlaxoSmithKline
- Abbott Laboratories
- Created
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2017-02-22Created from EPrint's datestamp field
- Updated
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2021-11-11Created from EPrint's last_modified field