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Published October 2004 | Published + Supplemental Material
Journal Article Open

Di-μ-acetato-κ^4O:O′-tetracarbonylbis(pyridyl-2-yl-κN-amine)diruthenium(I)(Ru—Ru)

Abstract

The structure of the title compound, [Ru_2(C_2H_3O_2)_2(C_5H_6N_2)_2(CO)_4], consists of a `sawhorse' diruthenium complex with two acetate bridges and two 2-amino­pyridine ligands in the axial positions, coordinating via the pyridine N atoms. A double-stranded hydrogen-bonded chain is formed via intra- and intermolecular hydrogen bonds involving the amine groups, one O atom of both acetate groups and two carbonyl O atoms.

Additional Information

© 2004 International Union of Crystallography. Received 26 August 2004. Accepted 2 September 2004. Online 11 September 2004. This work was supported by the Swiss National Science Foundation.

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Published - ci6437.pdf

Supplemental Material - ci6437.cif

Supplemental Material - sendsupfiles.txt

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Created:
August 19, 2023
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