Published September 15, 1993
| Published + Supplemental Material
Journal Article
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A Monodentate 1,3-Diphenyl-2-triazeno Terpyridineplatinum(II) Complex
Abstract
The compound (l,3-diphenyl-2-triazeno )(2,2',2"- terpyridine)platinum(II) perchlorate dimethylformamide solvate (1) is formed by reaction of dpt (dptH = 1,3-diphenyltriazene) and [Pt(tpy)Cl]Cl (tpy = terpyridine) in the presence of excess base (NEt3). There are two independent cations in the asymmetric unit. The platinum centers have a monodentate triazeno ligand with the remaining coordination sites occupied by the terpyridine group. The crystal packing is dominated by π-π stacking interactions, and metal-metal interactions are conspicuously absent.
Additional Information
© 1993 International Union of Crystallography. Received 30 September 1992; accepted 1 March 1993. We thank Marilyn M. Olmstead for assistance. This work was supported by an NSERC (Canada) postdoctoral fellowship to JAB, a 1991 NSF postdoctoral research fellowship in chemistry (No. CHE-9101931) to VJC, and grants from the National Science Foundation and the Office of Naval Research.Attached Files
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Additional details
- Eprint ID
- 70448
- Resolver ID
- CaltechAUTHORS:20160920-073747901
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- CHE-9101931
- NSF
- Office of Naval Research (ONR)
- Created
-
2016-09-29Created from EPrint's datestamp field
- Updated
-
2021-11-11Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Division of Chemistry and Chemical Engineering
- Other Numbering System Identifier
- 8734