Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published September 15, 1993 | Published + Supplemental Material
Journal Article Open

A Monodentate 1,3-Diphenyl-2-triazeno Terpyridineplatinum(II) Complex

Abstract

The compound (l,3-diphenyl-2-triazeno )(2,2',2"- terpyridine)platinum(II) perchlorate dimethylformamide solvate (1) is formed by reaction of dpt (dptH = 1,3-diphenyltriazene) and [Pt(tpy)Cl]Cl (tpy = terpyridine) in the presence of excess base (NEt3). There are two independent cations in the asymmetric unit. The platinum centers have a monodentate triazeno ligand with the remaining coordination sites occupied by the terpyridine group. The crystal packing is dominated by π-π stacking interactions, and metal-metal interactions are conspicuously absent.

Additional Information

© 1993 International Union of Crystallography. Received 30 September 1992; accepted 1 March 1993. We thank Marilyn M. Olmstead for assistance. This work was supported by an NSERC (Canada) postdoctoral fellowship to JAB, a 1991 NSF postdoctoral research fellowship in chemistry (No. CHE-9101931) to VJC, and grants from the National Science Foundation and the Office of Naval Research.

Attached Files

Published - hh1046.pdf

Supplemental Material - hh1046.cif

Files

hh1046.pdf
Files (441.0 kB)
Name Size Download all
md5:4c9e27059b367ae9607aaaf964aa7c4c
421.8 kB Preview Download
md5:d073ecd55ea6d6f9388babf9241bf4b9
19.2 kB Download

Additional details

Created:
August 20, 2023
Modified:
October 20, 2023