Published October 1996
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Journal Article
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A Diphenylcyclopropene Complex of Tungsten, [WCl_2O(PMePh_2)_2(η^2-3,3-diphenylcyclopropene)], Precursor to a Tungsten–Oxo–Olefin Metathesis Catalyst
Abstract
The title compound, dichlorobis(methyldiphenylphosphine-P) [(1,2-[η])-3,3-diphenylcyclopropene]oxotungsten, [WCl_2O(C_(15)H_(12))(C_(13)H_(13)P)_2], is a mononuclear complex of tungsten with an approximately octahedral environment around the metal atom. The ligand, 3,3-diphenylcyclopropene, is bonded to the W atom in a [η]^2-geometry with effectively identical metal-to-carbon bond distances [W-C1 = 2.133 (7) Å and W-C2 2.131 (7) Å].
Additional Information
© 1996 International Union of Crystallography. Received 6 March 1996; accepted 15 May 1996. The authors thank the NSF for Grant CHE-8219039 to purchase the diffractometer.Attached Files
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Supplemental Material - bk1246.cif
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Additional details
- Eprint ID
- 70318
- Resolver ID
- CaltechAUTHORS:20160913-131133401
- CHE-8219039
- NSF
- Created
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2016-09-13Created from EPrint's datestamp field
- Updated
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2021-11-11Created from EPrint's last_modified field