Published May 28, 2008
| Supplemental Material
Journal Article
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Direct Observation of the Primary Bond-Twisting Dynamics of Stilbene Anion Radical
- Creators
- Lee, I-Ren
- Bañares, Luis
- Zewail, Ahmed H.
Abstract
The anion radicals of stilbenes in the collisionless isolated phase were synthesized by electron attachment, and their dynamics were observed in real time on the femtosecond time scale. The observed coherent vibrational motion (∼42 cm^(−1)) and the primary bond-twisting dynamics (∼650 fs) for the D_2 state are on a vastly different time scale from that reported (∼10 ns) in solution.
Additional Information
© 2008 American Chemical Society. Received March 14, 2008. Publication Date (Web): May 07, 2008. L.B. gratefully acknowledges Del Amo Foundation and Research Vice-rectorate (acción especial no. AE10/07-15604) of Universidad Complutense de Madrid for financial support of travel for a two months stay at Caltech and A.Z. for his hospitality. This work is supported by the National Science Foundation and the Air Force Office of Scientific Research.Attached Files
Supplemental Material - ja801926m-file004.pdf
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Additional details
- Eprint ID
- 69654
- DOI
- 10.1021/ja801926m
- Resolver ID
- CaltechAUTHORS:20160816-095602727
- AE10/07-15604
- Universidad Complutense de Madrid
- Air Force Office of Scientific Research (AFOSR)
- Created
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2016-08-16Created from EPrint's datestamp field
- Updated
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2021-11-11Created from EPrint's last_modified field