Published March 1, 1978
| public
Journal Article
Synthesis and direct spectroscopic observation of a 1,1-dialkyldiazene. Infrared and electronic spectrum of N-(2,2,6,6-tetramethylpiperidyl)nitrene
Abstract
We report here the synthesis and direct observation of a 1, 1-dialkyldiazene, N-(2,2,6,6-tetramethylpiperidyl)nitrene (3). The visible spectrum provides the first experimental information concerning the electronic structure of a 1, 1-dialkyldiazene. Moreover, the infrared spectrum provides evidence that there is considerable double bond character in the N=N bond, similar to a 1,2-diazene (2).
Additional Information
© 1978 American Chemical Society. Publication Date: March 1978. Received September 14, 1977. The authors are grateful to the National Science Foundation (CHE75-06776) and the donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research. We thank W. A. Goddard and J. H. Davis for their interest and helpful discussions during this work.Additional details
- Eprint ID
- 67110
- DOI
- 10.1021/ja00473a051
- Resolver ID
- CaltechAUTHORS:20160516-094147419
- CHE75-06776
- NSF
- American Chemical Society Petroleum Research Fund
- Created
-
2016-05-16Created from EPrint's datestamp field
- Updated
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2021-11-11Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Crellin Laboratory of Chemistry
- Other Numbering System Identifier
- 5664