Vibrationally resolved studies of the 2π photoionization of NO

Creators: Lynch, D. L.; Schneider, B. I.; Collins, L. A.; McKoy, V.; Huo, W. M.

Abstract

We report the results of studies of the vibrationally resolved photoelectron angular distributions and vibrational branching ratios for 2π photoionization of NO leading to the X ^1Σ^+ state of NO^+. These results were obtained using single-particle frozen-core Hartree-Fock continuum functions for the photoelectron. These studies assess the role of the kσ shape resonance in the 11–18 eV photon energy range where broad non-Franck-Condon structure has been observed. In addition we demonstrate the importance of obtaining both the photoelectron angular distributions as well as the total cross sections in elucidating the relevant resonance features.

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© 1988 Elsevier Science Publishers B.V. Received 31 March 1988. The authors would like to thank S.H. Southworth, A.C. Parr, J.E. Bardis, and J.L. Dehmer for helpful discussions and access to their experimental results prior to publication. Work at the California Institute of Technology was supported by NSF Grant number CHE 85.

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Vibrationally resolved studies of the 2π photoionization of NO

Abstract

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