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Published October 15, 1981 | public
Journal Article

Experimental and theoretical studies of the valence-shell photoionization cross sections of acetylene: strong autoionization in the (1π_u^(−1)) X^2Π_u partial channel

Abstract

Experimental studies of photoionizaiion cross sections in acetylene reveal the presence of a strong resonance in the (1π_u^(−1) X^2Π_u partial channel that is attributed on the basis of corresponding theoretical studies to autoionization of the valence (2σ_u^(−1)1π_g) b^1Π_u and (2σ_u^(−1)4σ_g)^1Σ_u^+ states.

Additional Information

© 1981 Elsevier. Received 6 July 1981. It is a pleasure to acknowledge the support of the National Science Foundation and of the Petroleum Research Fund, administered by the American Chemical Society. We also thank Professor Noel Hush for his kind hospitality to PWL at the University of Sydney, and the authors of ref. [3] (or providing their results prior to publication.

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023