Published December 5, 1952
| public
Journal Article
The Infrared Spectra and Structure of the Chloramines and Nitrogen Trichloride
- Creators
- Moore, Gordon E.
- Badger, Richard M.
Abstract
The infrared vibration-rotation spectra of gaseous NH_2Cl, NHDCl, NDCl_2 and NCl_3 were investigated from 1.4 to 25µ. Several fundamental vibrations were identified, and the large rotational constants were evaluated for NH_2Cl, NHDCl and NHCl_2. With the assistance of reasonable assumptions regarding other parameters these were used to calculate an H-N-Cl angle of 102° in NH,Cl, and suggest that ∠Cl-N-Cl = 106° and r_(N-CI) = 1.76 Å in NHCl_2. These parameters are interpreted on the basis of simple electronic considerations.
Additional Information
© 1952 American Chemical Society. Received June 9, 1952. We are indebted to Professor Verner Schomaker for discussions regarding structural considerations.Additional details
- Eprint ID
- 62028
- DOI
- 10.1021/ja01143a073
- Resolver ID
- CaltechAUTHORS:20151110-112449953
- Created
-
2015-11-10Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 1696