Published January 15, 1994
| public
Journal Article
Studies of photoionization dynamics of methylidyne, imidogen, and hydroxyl radicals at near-threshold photoelectron kinetic energies
- Creators
- Wang, Kwanghsi
- Stephens, J. A.
- McKoy, V.
Abstract
We discuss results of theoretical studies of rotationally resolved photoelectron spectra of the CH, NH, and OH radicals, including predictions of zero-kinetic-energy (ZEKE) spectra for molecular ions produced via resonance enhanced multiphoton ionization. The influence of dynamical features such as Cooper minima, orbital evolution, and 1 mixing are examined for photoionization of the 3σ Rydberg orbital in these radicals. We also make specific predictions for the photoelectron spectra for each molecule within the context of current experimental capabilities.
Additional Information
© 1994 American Chemical Society. Received: August 5, 1993; In Final Form: October 20, 1993. This work was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We acknowledge the use of resources of the Jet Propulsion Laboratory/California Institute Technology CRAY Y-MP2E/116 SupercomputerAdditional details
- Alternative title
- Studies of Photoionization Dynamics of CH, NH, and OH Radicals at Near-Threshold
- Eprint ID
- 62027
- Resolver ID
- CaltechAUTHORS:20151110-111102505
- Air Force Office of Scientific Research (AFOSR)
- Department of Energy (DOE)
- Created
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2015-11-10Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 8836