Published 1969
| public
Journal Article
Nuclear magnetic resonance spectroscopy ^(13)C Spectrum of a Dimer of Cyclooatatetraene
- Creators
- Grohmann, K.
- Grutzner, J .B.
- Roberts, John D.
Abstract
The structure of the cyclooctatetraene dimer of m. p. 53° has been a matter of controversy. Structure I was proposed by Jones(3} and could be reconciled with a proposed mechanism of conversion of the dimer to bullvalene(4). Schröder(5) has proposed structure II because the material afforded the all cis-cyclobutanetetracarboxylic acid on ozonolysis and peracid oxidation. However, there is still a possibility that I could yield ciclobutanetetracarboxilic acid on oxidation by way of its valence tautomer III.
Additional Information
© 1969 Pergamon Press. Received in USA. 27 January 1969; received in UK for publication 6 February 1969. Supported by the National Science Foundation and USPHS Research Grant 11072-06 from the Division of Medical Sciences. Contribution No. 3801.Additional details
- Eprint ID
- 61519
- DOI
- 10.1016/S0040-4039(01)97697-X
- Resolver ID
- CaltechAUTHORS:20151026-093705693
- NSF
- GM-11072-06
- U.S. Public Health Service (USPHS)
- Created
-
2015-10-26Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 3801