Published February 1, 1956
| public
Journal Article
Small-Ring Compounds. XII. The Bromine Addition Products of Methylenecyclobutane
- Creators
- Applequist, Douglas E.
- Roberts, John D.
Abstract
The dibromide(s) (I) from addition of bromine to methylenecyclobutane has been studied by several worker but the structural evidence is confusing and inconclusive. Compound I has been reported to be reconverted to methylenecyclobutane by treatment with zinc and hydrolyzed to cyclopentanone in the presence of lead dioxide. It reacts with potassium cyanide in aqueous ethanol to give an unidentified dinitrile and with dimethylamine or trimethylamine to give both saturated (permanganate) and unsaturated products in which both bromines are displaced.
Additional Information
© 1956 American Chemical Society. Received August 22, 1955. Supported in part by the Petroleum Research Fund of the American Chemical Society. National Science Foundation Predoctoral Fellow, 1953-1955.Additional details
- Eprint ID
- 61382
- DOI
- 10.1021/ja01585a046
- Resolver ID
- CaltechAUTHORS:20151021-125952929
- American Chemical Society Petroleum Research Fund
- NSF Predoctoral Fellowship
- Created
-
2015-10-21Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2026