Published February 1, 1956
| public
Journal Article
The Reactions of 3-Phenyl-1-propylamine-1-^(14)C and 3-(p-Methoxyphenyl)-1-propylamine-1-^(14)C with Nitrous Acid
- Creators
- Fort, Arthur W.
- Roberts, John D.
Abstract
3-Phenyl-l-propylamine-l-^(14)C reacts with nitrous acid in aqueous solution to give hydrocinnamyl alcohol, benzylmethyl-carbinol and allylbenzene. Under similar conditions, 3-(p-methoxyphenyl)-l-propylamine-l-^(14)C gives p-methoxyhydro-cinnamyl alcohol, p-methoxybenzylmethylcarbinol and p-,ethoxyallylbenzene. A negligible amount of isotope-position rearrangement attends the formation of the above products. The course of the reactions of 3-aryl-1-propylamines with nitrous acid discussed.
Additional Information
© 1956 American Chemical Society. Received May 23, 1955. Supported in part by the program of research of the U. S. Atomic Energy Commission and the Petroleum Research Fund of the American Chemical Society. National Science Foundation Predoctoral Fellow, 1952-1954.Additional details
- Eprint ID
- 61379
- DOI
- 10.1021/ja01584a020
- Resolver ID
- CaltechAUTHORS:20151021-112215335
- Atomic Energy Commission
- American Chemical Society Petroleum Research Fund
- NSF Predoctoral Fellowship
- Created
-
2015-10-21Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 1996